Note to Fox News: it wasn't a cloud of toxic chlorine.
By Francie Diep
So you probably know it's not a good idea to swim in a pool with liquid nitrogen. You might not know exactly why—we'll discuss this further ahead—but it just sounds like a bad idea, right?
Right. German liquor company Jägermeister recently hosted a party in Mexico, during which staffers poured what appeared to be numerous 10-liter dewars of liquid nitrogen into the water, creating a foggy effect. In videos, you can hear partiers "Woo!"-ing… and then, not two minutes later, those not in the water pointing and saying, in Spanish, "Somebody's fainted. Someone else has fainted." Another video shows partiers jumping into the pool to pull limp bodies out of the water.
What happened? Not what others have reported, according to ChemBark, a blog by St. Louis University chemist Paul Bracher. Fox News Latino, the U.K.'s the Daily Mail, KTLA and others have said the nitrogen reacted with chlorine in the pool to form a "toxic cloud."
"This is almost certainly incorrect," Bracher wrote. Actually, molecular nitrogen is inert and shouldn't react with anything in the pool, he said. Instead, the nitrogen displaced oxygen from the air above the pool, "leaving none for the swimmers to breathe." Yipes!
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http://www.popsci.com/science/article/2013-06/why-having-liquid-nitrogen-pool-party-bad-idea
There is no "almost certainly" about it. N2 is essentially inert unless very high energies are applied to it, or certain catalysts (biological or otherwise).