Figure 1 A schematic of the fractional distillation of crude oil used in petroleum refining. The mixture is separated into Gases, Gasoline, Kerosene, Fuel oil, Lubricating oil, and Residue(asphalt).
This is an image modified from a source image on Wikimedia Commons
Following is a short overview of the the different fractions from petroleum:
(Natural) Gases
The gas fraction contains hydrocarbons containing 1 to 4 carbon atoms in each molecule. These can be used for fuels. Another use is to derive materials such as plastics and synthetic fibers from such hydrocarbons, accomplished by polymerization techniques. An example is given below, propane:
Propane
Gasoline
Probably the most familiar of the hydrocarbon distillates is gasoline. Gasoline consists of hydrocarbons with 5 to 12 carbon atoms in each molecule. It is difficult to overstate the importance of gasoline to modern society, given the central role of automobile travel in our society. Gasoline also serves as an industrial solvent. An example of a hydrocarbon found in gasoline is toluene:
Toluene
Kerosene
Kerosene consists of hydrocarbons containing between 12 and 16 carbon atoms per molecule. The foremost uses of kerosene are as lamp oil, diesel fuel, and for catalytic cracking, a processes discussed in the section on unsaturated hydrocarbons. This allows these larger hydrocarbons to be broken down to a size that can be used for gasoline. An example of a hydrocarbon that would be in the kerosene fraction is tetradecane:
Tetradecane
Fuel Oil
Fuel Oils consist of hydrocarbons ranging between 15 and 18 carbon atoms per molecule. Like kerosene, this distillate is used for heating oil, for diesel fuel, and for catalytic cracking. An example is hexadecane:
hexadecane
Lubricating Oil
Lubricating oils consist of 16 to 20 carbon atoms per hydrocarbon molecule. Referred to sometimes as mineral oil, lubricating oils are used to decrease friction between moving parts. Perhaps the most familiar application is motor oil. An example of a hydrocarbon in the size range for lubricating oil is eicosane:
Eicosane
Residue(asphalt)
Hydrocarbons which are not boiled away remain after the distillation as hydrocarbons with more than 20 carbon atoms per molecule. These hydrocarbons can be used as asphalt. An example is tetracosane.
http://chemed.chem.wisc.edu/chempaths/GenChem-Textbook/Organic-Compounds-Hydrocarbons-581.html