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ProfessorGAC

(75,697 posts)
20. Only Sort Of
Wed Jul 25, 2012, 11:23 AM
Jul 2012

Because of the unsaturation in the chains, gas will undergo mild oxidation when exposed to the atmosphere for a long time.

It will form some varnishes, aldehydes, ketones, and carboxylates. But, since those are still going to be low molecular weight, they'll still burn. They won't be as flammable, but still very combustible.

Gas used to varnish much worse, but the distillation processes have improved to the point that the lighter "enes" are lower in concentration.

Since aldehydes and acids can polymerize, you can get some filming. That's why a lawn mower might not start in the spring if you've left gas in the carborator all winter. The little orifice can get plugged with the varnish and the polymers. But a bulk storage of gasonline won't form enough of that to matter much.

GAC

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Some properties (anti-static additive, etc.) do degrade but it's still gasoline. LiberalLoner Jul 2012 #1
The more volatile molecular elements that make up gasoline will vaporize over time. Ikonoklast Jul 2012 #2
How do we know? Iggy Jul 2012 #6
There is degradation of octane number over time. Ikonoklast Jul 2012 #7
Any available, store bought additives Iggy Jul 2012 #9
I use Sta-Bil, and have had very good results with it. Ikonoklast Jul 2012 #15
OK Cool Iggy Jul 2012 #23
Does propane last longer? Ilsa Jul 2012 #14
I do not think propane brakes down... belcffub Jul 2012 #17
Simple answer: Yes, gasoline does degrade. MercutioATC Jul 2012 #3
If typical retail gasoline sits in a gas tank for long enough, it will not run an engine. Trillo Jul 2012 #4
If you want to keep gasoline for more than six months, or so, you have to add a chemical stabilizer leveymg Jul 2012 #5
Stabil should be used in gasoline which will be sitting around pipoman Jul 2012 #8
This is something I've had a whole lot of experience with 1-Old-Man Jul 2012 #10
All I know is the times I left gas in my mower Gman Jul 2012 #11
Water in the line. Pretty typical. HopeHoops Jul 2012 #13
You Got Lucky, If That's All You Did ProfessorGAC Jul 2012 #21
Makes sense in that Gman Jul 2012 #32
It's still viable as long as it isn't mixed with oil (two-cycle fuel). HopeHoops Jul 2012 #12
Which book? Javaman Jul 2012 #16
EARTH ABIDES, published 1949. Great book. raccoon Jul 2012 #18
Oh ugh. We'll have to differ on that book. Javaman Jul 2012 #19
Earth Abides is a grand book for the target reader - teens Brother Buzz Jul 2012 #22
The canned goods business, I agree there. It would be tasteless if not dangerous. raccoon Jul 2012 #26
Only Sort Of ProfessorGAC Jul 2012 #20
Yes, when my lawnmover sits over the winter... HooptieWagon Jul 2012 #24
Sad to see someone mention the ridiculous ethanol conspriacy theory here gregoire Jul 2012 #30
Personal experience, not conspiracy. HooptieWagon Jul 2012 #31
thanks, very interesting. all the gasoline i see here has ethanol. i don't know where to get 100% HiPointDem Jul 2012 #33
I wonder how that applies to C-Rats and other preserved food malthaussen Jul 2012 #25
I remember eating C-Rations back in 1985 that were Callmecrazy Jul 2012 #27
Yeah, I had C's in the '70s that went back to the Korean War. malthaussen Jul 2012 #29
Going to depend upon which gasoline it is? One_Life_To_Give Jul 2012 #28
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