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probably a heart attack or stroke. The stuff broke as he was falling down. Not know the configuration of the room/window and broken items I would guess that the window may have been broken in an attempt to get someone's attention for help.
The jell substance in the sink that smelled like tobacco, was he using an e-cig? Could it possibly vomit? some people vomit when having a medical emergency.
Sorry to hear about your friend. 
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