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jberryhill

(62,444 posts)
35. What industry would that be?
Mon Mar 4, 2019, 08:34 AM
Mar 2019

Last edited Mon Mar 4, 2019, 11:07 AM - Edit history (2)

"the article does not describe his invention.

i've been working in this industry for over 30 years."

Is it common in your industry, when informed that a Roger Gordon in Canada has a patent on ammonia synthesis, to be uninspired to find that patent within, literally, the seconds it takes to type "Roger Gordon ammonia patent" into Google in order to obtain a detailed description of exactly how it works?

https://patents.google.com/patent/US20110243828A1/en

I mean, granted, I haven't worked directly in engineering for a while, but I seem to recall that engineers and scientists tended to be pretty rabidly curious about stuff like this, and would usually take a look into it before opining about an article in the popular press about a garage inventor being hailed as yet another energy and environmental savior. At least I did.

Without even getting into the details, what does your industry experience tell you about how to perform these steps:

"A process for producing ammonia from air and water comprises producing nitrogen gas from air by pressure-swing-adsorption; producing hydrogen gas by electrolysis of water; compressing the nitrogen gas in a first cylinder to produce pressurized nitrogen gas; compressing the hydrogen gas in a second cylinder to produce pressurized hydrogen gas; compressing a mixture of the pressurized nitrogen and hydrogen gases in a third cylinder; heating the compressed mixture in the presence of a catalyst to react nitrogen and hydrogen to form ammonia; and extracting the ammonia from the mixture. "

You are doing electrolysis of water to get hydrogen, running a PSA reactor for the nitrogen, compressing the products of those processes and then heating the compressed mixture in the presence of a catalyst.

Again, while you didn't specify the industry with which you are familiar, you don't get to run these processes for free. You are not going to go from N2 and H2 to get NH3, so that you can burn the NH3 as fuel, without putting more energy into that process than you are getting out of it. That energy has to come from somewhere. If it is coming from solar, wind or hydro, it is a fair bet (actually something of a sure thing) that you can do better with the solar, wind or hydro directly, than by using that energy for an inefficient process to produce an inefficient combustible fuel. Unless, and only unless, for some reason there is a vehicle which you have to run and which cannot have an electric motor.

Processes which use energy to synthesize fuel are properly characterized as chemical energy storage processes. There's no "extra energy" to be had.

Another thing that can be gleaned from article is that the best area of application is believed to be remote areas. Why? Aside from the outstandingly hazardous basic idea here which might make more sense in a setting in which some hazardous industrial operation is already going on with the use of internal combustion engines (making access to fuel an issue), it is something of a ridiculous process for economical production of NH3 at scale, when there are less costly ways to do it (which use, i.e. better precursors and less energy). Since the inputs here are air and electricity, then there may be situations where the efficiency and energy costs of this process make sense if there is no other way to get vehicular fuel, but one has enough solar, wind or coal power to make electricity.

Obviously, if one is in an environment where electricity is plentiful and the motive power of specialized vehicles is not an issue, then you might as well run electric vehicles instead of using the electricity to run this scheme in order to produce a dangerous fuel at a higher energy than other methods.

Recommendations

0 members have recommended this reply (displayed in chronological order):

Interesting Sherman A1 Mar 2019 #1
I thought it was pretty interesting, sounds promising - and something that we won't hear on the news Rhiannon12866 Mar 2019 #2
We won't hear about it as you say Sherman A1 Mar 2019 #3
And the environment really ought to be at the forefront of news these days Rhiannon12866 Mar 2019 #4
Precisely Sherman A1 Mar 2019 #5
...because it isn't in the interests of watoos Mar 2019 #11
Precisely Sherman A1 Mar 2019 #14
It's a mixed blessing. TexasTowelie Mar 2019 #7
Thanks for the information Sherman A1 Mar 2019 #13
While it may reduce carbon emissions there will be a tradeoff. TexasTowelie Mar 2019 #6
Thanks for weighing in! Rhiannon12866 Mar 2019 #8
Yep, NOx is just as bad as SOx. KY_EnviroGuy Mar 2019 #9
"Unless they use solar or wind to power the ammonia machines..." jberryhill Mar 2019 #22
And, when questioned on that little detail, they would say.... KY_EnviroGuy Mar 2019 #33
according to the article garybeck Mar 2019 #34
What industry would that be? jberryhill Mar 2019 #35
Drive past a Oil Refinery CDerekGo Mar 2019 #26
Yes, and I've worked in a number of them. KY_EnviroGuy Mar 2019 #32
Here you go.... jberryhill Mar 2019 #36
Thank you, JBH. A very interesting design. KY_EnviroGuy Mar 2019 #38
It would be good on farm use where you don't have to "punch it." 3Hotdogs Mar 2019 #15
I've never understood why farms don't run on algae oil? Finishline42 Mar 2019 #27
True, but... TreasonousBastard Mar 2019 #17
Great idea tiptonic Mar 2019 #10
Bingo. watoos Mar 2019 #12
Catch and kill isn't only for the news media mitch96 Mar 2019 #28
How do they manage to do that jberryhill Mar 2019 #37
Ammonia is another energy storage chemical. Energy storage requires a source of primary energy. NNadir Mar 2019 #16
OK, that puts a different spin on it. TreasonousBastard Mar 2019 #18
I was waiting for you to comment on this thread. TexasTowelie Mar 2019 #19
I see you commented along similar lines above. The biggest issue I see with Haber-Bosch... NNadir Mar 2019 #23
Thanks for the summary exboyfil Mar 2019 #20
Thanks for the emphasis on the 2nd law of thermodynamics - you can't get something for free erronis Mar 2019 #21
Thank you NNadir, I always learn something from your posts. And aside from the refresher c-rational Mar 2019 #24
Excellent rebuttal. defacto7 Mar 2019 #29
My first thought was about safeinOhio Mar 2019 #25
This brings back a funny memory to me. Many years ago justhanginon Mar 2019 #30
Ammonia is commonly used as a refrigerant in the agricultural industry. hunter Mar 2019 #31
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